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Development and initial testing of an empirical forcefield for
Mar 6, 2008 ... exchange simulations of the conformation of PATs in implicit solvents. ... Conductive polymers from the polythiophene (PT) family have attracted interest in numerous domains, including ...... Komolov, K. Norgaard, The conformation of poly (3-dodecyl thiophene) within methacrylic polymer matrix, J. Polym.
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Nanoparticles of Conjugated Polymers - American Chemical Society
Aug 4, 2010 ... Nanoparticles composed of the conjugated polymer poly[3,4- ... dispersed in a polymeric matrix, as well as other highly disperse ... excess of an aqueous solution of sodium dodecyl sulfate ... conformation in these particles, which accounts for the ... thiophene, 2b, were obtained by addition of THF solutions.
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Full-Text - MDPI
Jan 9, 2012 ... In this section, azobenzene polymers that show macroscopic changes .... formation by tailored droplets or poly(methyl methacrylate) particles in ... opal, the spherical parts are filled by air, and residual part is formed by the matrix. ..... poly( 3-dodecylthiophene), a popular p-type organic semiconductor was ...
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Interdiffusion and Spinodal Decomposition in Electrically - MDPI
Aug 4, 2015 ... interdiffusion in conducting polymer blends, we show that a systematic ... to our previous studies, poly(3-dodecylthiophene) (P3DDT) was shown to be ... in conformational changes in the P3DDT backbone. ... evidenced as a solvatochromic shift in the UV-spectrum, when diluting P3DDT in the EVA 20 matrix.
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Get PDF (603K) - Wiley Online Library
Handbook of Thiophene-Based Materials: Applic ations in Organic ... AMLCDs, see active-matrix liquid crystal displays ..... syn and anti conformations of, 85–6 cyclotri(3 ..... methacrylate polymers, 17 ..... P3DDT, see poly(3-dodecylthiophene ).
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PDF(112K) - Wiley Online Library
Semiconducting Polymer Composites: Principles, Morphologies, Properties and ..... P3HT thin-film conformation 95 .... in polymer matrix 279, 280 ..... ( dimethylamino)ethyl methacrylate] block ... poly(3-dodecylthiophene) (P3DDT) 30 polyesters ...
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Influence of Molecular Conformations and Microstructure on the
Mar 19, 2014 ... organic devices fabricated with conjugated polymers in terms of charge mobility, .... One of the most widely studied conjugated polymers is poly(3-hexylthiophene) (P3HT). ... poly(2,5-bis(3-dodecyl-2-yl)thieno[3,2-b]thiophene) [51] align ..... MEH- PPV aggregate in a poly(methyl methacrylate) host matrix are ...
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absorption coefficients 372, 378 absorption intensity - Wiley-VCH
Semiconducting Polymer Composites: Principles, Morphologies, Properties and ..... P3HT thin-film conformation 95 .... in polymer matrix 279, 280 ..... ( dimethylamino)ethyl methacrylate] block ... poly(3-dodecylthiophene) (P3DDT) 30 polyesters ...
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Light-Emitting Polythiophenes
luminescence efficiency (ΦPL) of poly(3-alkylthiophenes). (PATs) is ... low temperatures to a random-coil conformation when the temperature is ... The FeCl3-mediated polymerization of thiophene in chloro- form was .... higher emission efficiency of 0.2% for dodecyl-substituted ..... polymer into an inert solid matrix. Thus ...
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Full Text (PDF)
Aug 25, 2015 ... into weakly ordered fibers within an inert polymer matrix without affecting their ... In this respect, poly{[N,N′-bis(2-octyldodecyl)-1,4,5,8-naphtha- lenediimide-2 ... angle between the NDI and thiophene units (13). Whereas a face- .... originates mainly from a change in the backbone conformation induced by ...
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Photonics and Nonlinear Optics with Molecular Materials and
in an amorphous polymer matrix and as a side chain of the same ... contributions new methacrylate polymers containing the N-alkyl pyridinium salt in the side .... conformation coil to rod transition at the air-water interface was shown to depend on the .... prepared poly(3-dodecylthiophene) by the degenerate four wave mixing ...
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Polypyrrole
Jan 13, 2005 ... There are several simple ways to make the polymer with controlled ... permittivity changes rapidly with the amount polypyrrole in the ... Materials that will be studied include polypyrrole powders dispersed in a matrix, latex coated ..... This has been noted to yield higher conductivity in the case of poly 3,4-. 4.
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Physical Chemistry Chemical Physics - RSC Publishing
Feb 18, 2011 ... interfaces applied in polymer assembly can often add new ... Janus silica particles.2 A polar poly(sodium methacrylate) ..... the brush conformation can be altered, for example poly- .... technique with colloidal lithography to form poly(3,4- ethylene- .... following removal of the silica matrix from the silica-MIP.
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SYMPOSIUM EE Electroactive Polymers and Their Applications as
Department of Chemistry, Polymer Program, Institute of Materials. Science ... conformation change of structure by the delocalization of -electrons ... behaviors in head-tail poly(3-alkylthiophene) (HT-PAT) with alkyl = ... polyethyleneoxide in the matrix where the material remains ..... to a methacrylate polymer backbone.
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Preparation, properties and applications of polypyrroles
tion, properties and applications of PPYs are reviewed in this paper. ... Keywords: Polypyrrole; Oxidatively chemical polymerization; Electrochemical ..... The oxidative matrix polymerization of ... pare soluble poly (3-substituted pyrrole) and ... instance, PPY doped by p-dodecylbenzene sul- ..... presence of thiophene [81].
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Transparent electrodes based on conducting polymers for display
Jun 10, 2013 ... polymers in display technologies is their use as transparent elec- ... polyaniline ( PANI), polypyrrole (PPY) and poly(3,4-ethylenedioxy- thiophene) (PEDOT) are the three most important conducting poly- mers. .... The conformation adopted by conducting polymers can affect ... p-dodecylbenzeneulfonate. Fig.
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PDF - Beilstein-Institut
Feb 2, 2012 ... Moreover, poly(3-hexylthiophene) (P3HT) chains were further .... solvents, as well as in various polymer matrices and nanocom- ... in DDPO4-imogolite compared with the neat dodecylphos- .... Recently, we reported the grafting of poly(methyl methacrylate) ..... rodlike conformation in the solution [87].
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Rational Design of Versatile Self-Assembly Morphology of Rod-Coil
the rod-rod interaction, rod-coil interaction and conformational asymmetry. ... using poly(3-alkylthiophene)-b-poly(methyl methacrylate) as a model. ... from linear hexyl to longer dodecyl and to branch 2-ethyl hexyl, both rod-coil and ... scientists to manipulate and obtain the desired order morphology in high .... PMMA matrix.
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Inkjet Printing-Process and Its Applications - SEAS
Aug 25, 2009 ... inkjet printing, which in our opinion, offer the greatest advance in their ..... trenches in polymethyl methacrylate (PMMA) with a separation of 250 nm (which ... poly(2,5-bis(3-dodecylthiophene-2-yl)thieno[3,2-b]thiophene) (pBTTT) to obtain .... properties of the nanocrystals in embedded polymer matrix, PVA.
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Reference - 京都大学原子炉実験所
December, 2006, the 2nd meeting was held at Wulai, Taiwan in December, 2007, the 3rd ... poly(3,4-ethylenedioxy-2,5-thiophene):poly(styrene sulfonate).
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